Asymmetric Synthesis of 6-Carbomethoxyethyl-6-Methyl-ε-Caprolactone
نویسندگان
چکیده
منابع مشابه
(S)-6-Methyl-∊-caprolactone
The chiral title compound, C(7)H(12)O(2), a lactone derivative, features a seven-membered ring that adopts a chair conformation. The crystal structure is stabilized by weak C-H⋯O inter-actions occurring in the (100) plane. The absolute configuration was assigned on the basis of the enantioselective synthesis.
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The biodegradability and biocompatibility properties of ε-caprolactone homopolymers place it as a valuable raw material, particularly for controlled drug delivery and tissue engineering applications. However, the usefulness of such materials is limited by their low hydrophilicity and slow biodegradation rate. In order to improve polycaprolactone properties and functionalities, copolymerization ...
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ژورنال
عنوان ژورنال: Journal Of The Brazilian Chemical Society
سال: 1996
ISSN: 0103-5053
DOI: 10.5935/0103-5053.19960064